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991.
Palytoxin, one of the most toxic non-peptide substances, formed an associated dimer of 5 nm length in aqueous solution. 相似文献
992.
A stable guanine-substituted nitronyl nitroxide radical 1 has been synthesized and characterized. The single-crystal structure analyses and magnetic susceptibility measurements exhibit a one-dimensional architecture of guanine base resulting from carbonyl-amino hydrogen bonds in the solid state, giving a 1D ferromagnetic chain of the radical moieties. 相似文献
993.
Murata T Morita Y Yakiyama Y Nishimura Y Ise T Shiomi D Sato K Takui T Nakasuji K 《Chemical communications (Cambridge, England)》2007,(39):4009-4011
The reaction between an imidazole-functionalized EDT-TTF and F(4)TCNQ produced a zwitterionic pi-radical, which formed a self-assembled structure by the cooperation of hydrogen-bonds and multiple S...S interactions and exhibited three-step oxidation processes and a high electrical conductivity as a single-component organic molecule. 相似文献
994.
Nanjo D Hosoi H Fujino T Tahara T Korenaga T 《The journal of physical chemistry. B》2007,111(11):2759-2764
Femtosecond/picosecond time-resolved fluorescence study of hydrophilic polymer fine particles (polyacrylamide, PAAm) was reported. Ultrafast fluorescence dynamics of polymer/water solution was monitored using a fluorescent probe molecule (C153). In the femtosecond time-resolved fluorescence measurement at 480 nm, slowly decay components having lifetimes of tau(1) approximately 53 ps and tau(2) approximately 5 ns were observed in addition to rapid fluorescence decay. Picosecond time-resolved fluorescence spectra of C153/PAAm/H2O solution were also measured. In the time-resolved fluorescence spectra of C153/PAAm/H2O, a peak shift from 490 to 515 nm was measured, which can be assigned to the solvation dynamics of polymer fine particles. The fluorescence peak shift was related to the solvation response function and two time constants were determined (tau(3) approximately 50 ps and tau(4) approximately 467 ps). Therefore, the tau(1) component observed in the femtosecond time-resolved fluorescence measurement was assigned to the solvation dynamics that was observed only in the presence of polymer fine particles. Rotational diffusion measurements were also carried out on the basis of the picosecond time-resolved fluorescence spectra. In the C153/PAAm/H2O solution, anisotropy decay having two different time constants was also derived (tau(6) approximately 76 ps and tau(7) approximately 676 ps), indicating the presence of two different microscopic molecular environments around the polymer surface. Using the Stokes-Einstein-Debye (SED) equation, microscopic viscosity around the polymer surface was evaluated. For the area that gave a rotational diffusion time of tau(6) approximately 76 ps, the calculated viscosity is approximately 1.1 cP and for tau(7) approximately 676 ps, it is approximately 10 cP. The calculated viscosity values clearly revealed that there are two different molecular environments around the polyacrylamide fine particles. 相似文献
995.
The free-energy landscape of the Alzheimer beta-amyloid peptide Abeta(12-36) in a 40% (v/v) 2,2,2-trifluoroethanol (TFE)/water solution was determined by using multicanonical molecular dynamics simulations. Simulations using this enhanced conformational sampling technique were initiated from a random unfolded polypeptide conformation. Our simulations reliably folded the peptide to the experimental NMR structure, which consists of two linked helices. The shape of the free energy landscape for folding was found to be strongly dependent on temperature: Above 325 K, the overall shape was funnel-like, with the bottom of the funnel coinciding exactly with the NMR structure. Below 325 K, on the other hand, the landscape became increasingly rugged, with the emergence of new conformational clusters connected by low free-energy pathways. Finally, our simulations reveal that water and TFE solvate the polypeptide in different ways: The hydrogen bond formation between TFE and Abeta was enhanced with decreasing temperature, while that between water and Abeta was depressed. 相似文献
996.
This article focuses on the dependence of water uptake on the displacement, velocity, mechanical force, and charging profiles of perfluorinated ionomer-platinum/Li+-based actuators. Both the displacement and force generation were found to be strongly dependent on the humidity. The primary reason for this effect is a decrease in the stiffness as a result of the humidity. The actuators demonstrated a dramatic reverse motion and a negative force, and this subsequent relaxation was dramatically decreased by decreasing humidity. This relaxation process can be explained by the slow diffusion of water into the elastically softened anode and out of the stiffened cathode. There are no clear inflection points on the charging profile during the reverse relaxation, and this suggests that the relaxation process does not involve a major redistribution of counter cations. An increase in water uptake resulted in an enhancement of the velocity of the displacement. A continuous generation of force was also examined by scanning potential, and the force was proportional to the potential. Humidities near 50-60% (i.e., water uptakes of ca. 5 wt %) gave a better actuator bending performance. 相似文献
997.
Kubo T Shimizu A Uruichi M Yakushi K Nakano M Shiomi D Sato K Takui T Morita Y Nakasuji K 《Organic letters》2007,9(1):81-84
[reaction: see text] A new Kekulé polycyclic hydrocarbon with a singlet biradical index of 50% was synthesized. The singlet biradical character was assessed with UV and 1H-NMR spectroscopy, cyclic voltammetry, SQUID magnetic susceptibility measurement, and quantum chemical calculations. 相似文献
998.
With the aid of the extreme resolving power of Fourier-transform ion-cyclotron-resonance mass spectrometry (FT-ICR/MS), we
have developed a metabolomics platform for high-throughput metabolic profiling and metabolite candidate identification integrating
a data-processing system, the Dr.DMASS program (), and a metabolite-species database, KNApSAcK (). We discuss the potential of this FT-ICR/MS-based metabolic profiling scheme as a general metabolomics tool by clarification
of plant metabolic disorders and specific metabolite accumulation patterns caused by herbicidal enzyme inhibitors. 相似文献
999.
Nelsen SF Weaver MN Yamazaki D Komatsu K Rathore R Bally T 《The journal of physical chemistry. A》2007,111(9):1667-1676
The first few bands in the optical spectra of radical cations can often be interpreted in terms of A-type transitions that involve electron promotions from doubly occupied to the singly occupied molecular orbital (SOMO) and/or B-type transition which involve electron promotion from the SOMO to virtual molecular orbitals. We had previously demonstrated that, by making use of Koopmans' theorem, the energies of A-type transitions can be related to orbital energy differences between lower occupied MOs and the highest occupied MO (HOMO) in the neutral molecule, calculated at the geometry of the radical cation. We now propose that the energies of B-type transitions can be related similarly to energy differences between the lowest unoccupied MO (LUMO) and higher virtual MOs in the dication, also calculated at the geometry of the radical cation, by way of an extension of Koopmans' theorem to virtual MOs similar to that used sometimes to model resonances in electron scattering experiments. The optical spectra of the radical cations of several polyenes and aromatic compounds, the matrix spectra of which are known (or presented here for the first time), and for which CASSCF/CASPT2 calculations are available, are discussed in terms of these Koopmans-based models. Then the spectra of five poly(bicycloalkyl)-protected systems and that of hexabenzocoronene, compounds not amenable to higher level calculations, are examined and it is found that the Koopmans-type calculations allow a satisfactory interpretation of most of the features in these spectra. These simple calculations therefore provide a computationally inexpensive yet effective way to assign optical transitions in radical ions. Limitations of the model are discussed. 相似文献
1000.